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Ligroin is the petroleum fraction consisting mostly of C7 and C8 hydrocarbons and boiling in the range 90‒140 °C (194–284 °F). The fraction is also called heavy naphtha. Ligroin is used as a laboratory solvent. Products under the name ligroin can have boiling ranges as low as 60‒80 °C and may be called light naphtha.
The name ligroin (or ligroine or ligroïne) appeared as early as 1866.